Filename: H2OVIS.gz File type: ascii space delimited File content: Water vapor line parameters from 26000 to 13000 cm-1 DESCRIPTION: Columns are: Name Comment 1. Wvnb Vacuum wavenumber [cm-1] 2. Err 3sigma error on wavenumber 3. XS Absorption cross-section [cm-1/(molecule.cm-2)] @291.3 K 4. Err 3sigma error on the absorption cross-section 5. gLself Self-broadened halfwidth (HWHM) [cm-1/atm] @291.3 K 6. Err 3sigma error on the self-broadened halfwidth 7. gLN2 N2-broadened halfwidth (HWHM) [cm-1/atm] @291.3 K 8. Err 3sigma error on the N2-broadened halfwidth 9. gLAir Air-broadened halfwidth (HWHM) [cm-1/atm] @289.0 K 10. Err 3sigma error on the Air-broadened halfwidth 11. N2Pshift N2 frequency shift [cm-1/atm] @291.3 K 12. Err 3sigma error on the N2 frequency shift 13. AirPshift Air frequency shift [cm-1/atm] @289.0 K 14. Err 3sigma error on the Air frequency shift 15-17. J'K'aK'c Upper state assignment in the form J', K'a, K'c 18-20. J"K"aK"c Lower state assignment in the form J", K"a, K"c 21-23. v' Upper state vibrational quantum numbers in the form v'1, v'2, v'3 24-26. v" Lower state vibrational quantum numbers in the form v"1, v"2, v"3 27. E" Lower state energy [cm-1] 28. Flag Literature reference for rovibrational line assignments Flag (0) Not assigned Flag (1) N.F. Zobov et al., to be published 29. Flag Isotopomer identification from HITRAN2000 Flag (O18) H2{18}O 30. Com Specific comments to our linelist S = line saturated at 18.5 hPa of pure H2O; line parameters are provided, though not obtained in optimal conditions. REFERENCES: These data should be referred to as the Bxl-Reims H2O database, and to the corresponding papers: a) P.-F. Coheur, S. Fally, M. Carleer, C. Clerbaux, R. Colin, A. Jenouvrier, M.-F. Mérienne, C. Hermans, A. C. Vandaele, JQSRT, 74, 2002, 493-510. b) update with air-broadening and air-shifts: S. Fally, P.-F. Coheur, M. Carleer, C. Clerbaux, R. Colin, A. Jenouvrier, M.-F. Mérienne, C. Hermans, A. C. Vandaele, JQSRT, 82; 2003, 119-131. c) N.F. Zobov et al., to be published EXPERIMENTAL CONDITIONS - Instrument: portable high-resolution Fourier Transform spectrometer (Bruker IFS-120M) - Absorption path-length: 602 m - Spectral range: 26000-13000 cm-1 - Resolution: 0.06 cm-1 (MOPD: 15 cm) - Pressure: 18.5 hPa of pure H2O 170 to 802 hPa of N2+H2O pressure (with a constant H2O pressure of 18.5 hPa) 178 to 509 hPa of air+H2O pressure (with a constant H2O pressure of 9.75 hPa) - Temperature: room (290±2K) CAUTION - All line parameters are experimental values, which should be used with their associated errors - The reported errors are statistical errors resulting from the fitting procedure. An additional systematic error due to uncertainties on the pressure, the temperature and the path length should be considered for each parameter: deltaWvnb/Wvnb = ± 0.00002% deltaXS/XS = ± 2.5% deltagLself/gLself = ± 1% deltagLN2/gLN2 = ± 1% deltagLAir/gLAir = ± 1% deltaPshift/Pshift = ± 1% - The same format is used for the 2 linelists H2OVIS and H2ONIR that can therefore be merged. Due to the specificity of the 2 spectral regions, it is recommended to carefully read the 2 readme files and the associated papers, and to contact the person in charge in case of problem. - 23 lines have been fitted to a single line but were assigned to a doublet. The assignment corresponding to the line with the highest calculated intensity is given in the linelist, and the duplicate is listed below. Also given below is the ratio of the calculated intensities between the two duplicates. Wvnb XSratio J' K'a K'c J" K"a K"c v'1 v'2 v'3 v"1 v"2 v"3 E" 25022.2393 3.1 4 4 1 4 4 0 7 0 1 0 0 0 488.13417 22434.3660 15.5 4 3 1 5 2 4 7 0 0 0 0 0 416.20873 20605.0978 1.7 4 2 3 3 2 2 3 0 3 0 0 0 206.3014 19064.1843 3.0 4 3 2 3 3 1 2 1 3 0 0 0 285.21933 18956.2243 3.0 5 5 0 5 5 1 2 1 3 0 0 0 742.07308 17485.0566 1.7 4 2 2 3 0 3 1 2 3 0 0 0 136.76166 17470.9184 1.3 5 4 1 5 1 4 2 2 2 0 0 0 399.45753 17186.8547 2.9 10 0 10 11 0 11 2 0 3 0 0 0 1327.11014 16572.7521 11.3 4 1 4 5 2 3 1 4 2 0 0 0 446.51069 15696.7480 1.1 8 2 6 7 0 7 3 1 1 0 0 0 586.24358 15690.4203 2.9 5 0 5 6 0 6 1 1 3 0 0 0 446.69659 15655.4008 6.2 5 4 1 6 4 2 1 1 3 0 0 0 757.78023 15641.5204 3.1 5 5 0 5 5 1 0 3 3 0 0 0 742.07308 15201.7083 2.9 5 5 0 6 5 1 3 1 1 0 0 0 888.63271 14446.5852 3.0 13 0 13 12 0 12 1 0 3 0 0 0 1557.84462 14442.1898 3.0 11 0 11 10 0 10 1 0 3 0 0 0 1114.53231 14131.4278 3.1 3 0 3 4 2 2 1 0 3 0 0 0 315.77952 14053.0395 1.0 7 4 4 6 2 5 2 2 1 0 0 0 552.91143 14001.2038 3.6 5 1 5 4 0 4 1 2 2 0 0 0 222.05274 13998.8921 3.0 11 0 11 12 0 12 1 0 3 0 0 0 1557.84462 13873.1390 1.9 9 5 4 8 4 5 2 4 0 0 0 0 1122.70869 13732.0309 1.2 9 5 5 9 5 4 2 2 1 0 0 0 1477.29757 13708.0719 1.6 4 1 3 3 2 2 3 2 0 0 0 0 206.3014 CONTACT INFORMATION: Université Libre de Bruxelles Laboratoire de Chimie Quantique et Photophysique CP160/09 (formerly Laboratoire de Chimie Physique Moléculaire) Unité de Spectroscopie de l'atmosphère 50, Av. F. D. Roosevelt B-1050 Brussels BELGIUM http://www.ulb.ac.be/cpm/ tel: +32-2-650.24.15 (secr.) fax: +32-2-650.42.32 email: mcarleer@ulb.ac.be Université de Reims Champagne-Ardennes Groupe de Spectrométrie Moléculaire et Atmosphérique UPRESA 6089 UFR Sciences Moulin de la Housse BP1039 F-51687 Reims Cedex 2 FRANCE http://www.univ-reims.fr/Labos/ tel: +33.26.91.33.33 email: alain.jenouvrier@univ-reims.fr Institut d'Aéronomie Spatiale de Belgique 3, Av. Circulaire B-1180 Brussels BELGIUM http://www.oma.be/BIRA-IASB/ tel: +32-2.373.0.367 email: A-C.Vandaele@oma.be